Piezoelectric paint: Ceramic-polymer composites for vibration sensors

A piezoelectric ceramic-polymer composite has been developed for use as a novel thick film strain sensor for vibration monitoring of structures. The material is in the form of a paint that can be applied to a wide range of substrates using conventional spraying equipment. The sensor properties depend on the morphology of the composite and on the electrodes that are used to couple it to the charge amplifier. Electrodes of various kinds have been tested. Interaction between the electrode and the piezoelectric paint sometimes occurs (for example, the organic vehicle for spray-coated electrodes may interact with the paint binder). The morphologies of the piezoelectric paint and of the electrode materials have been studied using light optical microscopy and scanning electron microscopy to investigate the effect of different compositions and of different processing conditions (e.g., paint mixing schedule). Preliminary work is reported on the characteristics of the piezoelectric particles and on the effect of heat treatment applied to anneal out defects produced by milling. X-ray analysis and particle size analysis have been used to characterize the changes that take place on heat treatment. X-ray diffractometry has also been used to follow the effect of poling on the paint sensors. At the present state of development, sensors made using the paint have a dynamic range of at least 40–4000 microstrain and a bandwidth of at least 1 Hz–2 kHz, and piezoelectric coefficient d ₃₁ of approximately 20 pC/N. The sensors are resistant to outdoor exposure and a successful field trial has been conducted.     

Intramaze and Extramaze Cue Processing in Adult APPSWE Tg2576 Transgenic Mice.

The present study examined spatial and nonspatial learning in adult Tg2576 mice. Transgenic mice were impaired in acquisition of a T-maze forced-choice alternation task. However, mutant mice were as sensitive as control mice to the introduction of retention intervals and proactive interference, and this suggested that short-term memory processes were intact in Tg2576 mice. Probe trials revealed that the Tg2576 mice did not use an allocentric strategy to navigate to the goal arm. However, mutant mice acquired an intramaze brightness discrimination, a simple room discrimination, and a contextual biconditional left-right discrimination in a T maze. Results suggest that Tg2576 mice are able to process both intramaze and extramaze stimuli but are impaired in forming an allocentric representation of their environment. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Lipase catalyzed synthesis of polycaprolactone and clay-based nanohybrids

This study presents the use of original systems based on Candida antarctica lipase B (CALB) immobilized on montmorillonite and sepiolite nanoclays as efficient catalysts for the enzymatic polymerization of ε-caprolactone (ε-CL) and the in situ elaboration of nanohybrids.     

Performance evaluation of a submerged membrane bioreactor for the treatment of brackish oil and natural gas field produced water

Produced water, which is co-produced during oil and gas manufacturing, represents one of the largest sources of oily wastewaters. Therefore, treatment of this produced water may improve the economic viability and lead to a new source of water for beneficial use. In this study a submerged hollow fiber membrane bioreactor (MBR) has been studied experimentally for the treatment of brackish oil and natural gas field produced water. This type of wastewater is also characterized with relatively moderate to high amount of salt, oil and total petroleum hydrocarbons (TPH). However, the bacteria which are growing in conventional activated sludge and MBR cannot survive at these strict conditions, therefore acclimation of the bacteria is of vital importance. The performance of the biological system, membrane permeability, the rate and extent of TPH biodegradability have been investigated under different sludge age and F/M ratios. The results obtained by gas chromatography analyses showed that the MBR system could be very effective in the removal of TPH from produced water and a significant improvement in the effluent quality was achieved.     

Internet use and depression among older adults

The findings regarding the impact of Internet use on well-being are mixed and studies are often criticized due to small samples and lack of consistency in measurement. Fewer studies have examined this issue among older adults. The purpose of this study is to examine the relationship between Internet use and depression among retired Americans age 50 years or older. Using data from the Health and Retirement Survey, the study estimates the relationship between Internet use and depression through combined use of regression and propensity score methodologies. All empirical methods indicate a positive contribution of Internet use to mental well-being of retired older adults (?50 years), reducing depression categorization by approximately 20–28%.     

Impact of module design on the performance of membrane bioreactors treating municipal wastewater

Membranes are located in a membrane module that physically seals and isolates the feed stream from the permeate flux in membrane bioreactors (MBRs). Therefore, module type, structure, and geometrical configuration are critical design considerations affecting membrane performance in MBRs. In this study, impact of membrane module design on treatment and filtration performance of MBRs was investigated. For this purpose, two flat sheet membrane modules with different outlet structures and module geometries, including rectangular- and D-shaped, were tested. In addition to the differences in outlet structure and module geometry, size of circular structures which supported membranes in rectangular- and D-shaped modules differed from each other. Considering the results, permeate quality was not affected from the change in the module design. However, the most remarkable impact of the module design was observed on the transmembrane pressure (TMP) evolution and fouling potential. D-shaped membrane module including smaller circular structures resulted in a decrease in fouling potential and thus, this module could be operated longer time in comparison to rectangular-shaped membrane module without a severe TMP increase. The observed differences in TMP increase and fouling potential lead to the hypothesis that module design is a critical factor affecting filtration performance in MBRs.     

Structural and Physicochemical Properties of a Polymerizable Surfactant Synthesized from <Emphasis Type="Italic">N</Emphasis>-Methylol Acrylamide

A new polymerizable nonionic surfactant with reactive vinyl groups has been synthesized from N‐methylol acrylamide using a two‐step procedure. The structure of the surfactant molecule was characterized by Fourier transform infrared, ¹H nuclear magnetic resonance and mass spectroscopy. The surface active properties alongside its self‐assembly properties were investigated by surface tension, electrical conductivity, and fluorescence spectroscopy measurements. As compared with other nonionic surfactants, this study showed that this polymerizable surfactant possesses slightly a higher critical micelle concentration (CMC) value and the surface tension value at CMC. The obtained CMC values were compatible among measurements, ca. 0.02–0.038 M. The evidence of micelle formation also provided by the zeta potential measurements and the obtained zeta potential values showed that the polymerizable surfactant solutions had limited stability. The hydrolysis stability and solubility of the polymerizable surfactant were also investigated. The solubility results have shown that it was soluble in polar solvents while insoluble in nonpolar solvents both at room temperature and 40 °C. The acidic and basic hydrolysis of the surfactant increased as the temperature increased and the hydrolysis stability was 180 min (basic medium) and 55 min (acidic medium) at 80 °C.     

Assessment of obsessive-compulsive symptom dimensions: Development and evaluation of the Dimensional Obsessive-Compulsive Scale.

Although several measures of obsessive-compulsive (OC) symptoms exist, most are limited in that they are not consistent with the most recent empirical findings on the nature and dimensional structure of obsessions and compulsions. In the present research, the authors developed and evaluated a measure called the Dimensional Obsessive-Compulsive Scale (DOCS) to address limitations of existing OC symptom measures. The DOCS is a 20-item measure that assesses the four dimensions of OC symptoms most reliably replicated in previous structural research. Factorial validity of the DOCS was supported by exploratory and confirmatory factor analyses of 3 samples, including individuals with OC disorder, those with other anxiety disorders, and nonclinical individuals. Scores on the DOCS displayed good performance on indices of reliability and validity, as well as sensitivity to treatment and diagnostic sensitivity, and hold promise as a measure of OC symptoms in clinical and research settings. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Phase transformations,dislocations and hardening behavior in uniaxially compressed silicon nanospheres

Molecular dynamics has been used to simulate the uniaxial compression of single crystal silicon nanospheres using the Tersoff potential. The resulting yield behavior is shown to vary with changes in temperature, sphere size, and crystallographic orientation with respect to the loading direction. Only compression along the [1 0 0] crystallographic direction resulted in the formation of the β-Sn phase. A temperature dependent hardening response is observed in all orientations independent of the β-Sn phase transformation. Dislocation activity is detected at elevated temperatures in the largest sphere indicating a critical temperature and size for nucleation. Consequences of these dislocations to simulating strength properties at the nanoscale are discussed.